Synthesis and optoelectronic properties of novel fluorene-bridged dinuclear cyclometalated iridium (III) complex with A–D–A framework in the single-emissive-layer WOLEDs

To explore the influence of push–pull chromophores on properties of emitter in organic light-emitting devices (OLEDs), an acceptor–donor–acceptor (A–D–A)-based dinuclear iridium (III) complex of (dfppy)₄Ir₂(dipic-FL) was synthesized via Suzuki coupling reaction, in which dfppy is 2-(2,4-difluorophenyl)pyridine and dipic-FL is 2,7-di(5-pyridyl-2-carboxyl)-9,9-dioctyl-9H-fluorene. An intense emission peak at about 480 nm resulting from the (dfppy)₂Ir(pic) chromophore and a weak long-wavelength emission band at 580–660 nm attributed to intramolecular charge transfer transition were exhibited for (dfppy)₄Ir₂(dipic-FL) in dichloromethane solution. But a remarkably hypsochromic photoluminescence profile with an intense characteristical emission peak at 422 nm was observed, which is attributed to the intraligand (IL) π–π^∗ excited states in its thin film. White emission with a maximum luminance of 1040 cd/m² and current efficiency of 1.2 cd/A was obtained in its single-emissive-layer (SEL) OLEDs with a configuration of ITO/PEDOT:PSS/(dfppy)₄Ir₂(dipic-FL) (10 wt%):TCTA/TPBi/LiF/Al. To our knowledge, this is one of the best examples in term of dinuclear iridium complex as single dopant in the high-performance white-emitting SEL-OLEDs.     

移动基站电费管控措施探讨

从分析移动基站电费现状入手,深入研究了转供电改造模型的建立,通过对直供电改造中基站耗电量、电费单价、改造投资金额与投资回收年限关系的分析,提出直供电改造投资模型字典,可作为基站转供电改造选择依据,并对管理节能及电费管控的相关内容进行了深入研究。     

国际焊接人员资质认证授权20年及国际焊接企业认证授权10年来的发展

中德在焊接人员培训体系与焊接企业认证体系的多年合作为中国焊接体系与国际接轨、获取国际焊接学会授权奠定了基础;CANB,ATBs获得国际授权后,根据国内的实际情况,不断调整培养模式,促进国际焊接培训体系在国内的推广实施,20年来累计为国内培养了25000多名国际资质焊接专业人员(不含ISO 9606焊工等)。CANBCC获得国际授权10年来累计认证企业近600家,提升了焊接企业核心竞争力,促进了焊接企业高质量发展。     

Ti55钛合金整体壁板电脉冲辅助压弯成形失稳研究

高温钛合金网格筋壁板相较于传统的铝合金筋壁板结构效率更高,但是室温下钛合金整体壁板难以成形。利用电流电致塑性效应和焦耳热效应能有效降低成形载荷、提高成形极限,并且能有效避免钛合金在加热中被严重氧化。本研究建立了Ti55整体壁板电脉冲辅助压弯成形的电-热-力耦合有限元模型,并对不同成形工艺参数和壁板几何参数进行模拟。结果表明:在壁板两端施加8 A/mm~2电流密度时,压弯成形温度区间比较合适。整体壁板随着筋条高度的增加,失稳屈曲程度越来越大,筋条失稳时所需的临界载荷越小,筋条的稳定性越差。腹板厚度主要影响筋条的温度从而影响筋条的失稳情况。整体壁板纵向筋条间距增大,筋条稳定性越差,筋条失稳屈曲也越严重。     

Enhancement of Strength–Ductility Balance of the Laser Melting Deposited 12CrNi2 Alloy Steel Via Multi-step Quenching Treatment

A ferrite–austenite 12CrNi2 alloy steel additively manufactured by laser melting deposition(LMD) was heat treated by direct quenching(DQ) and tempering inter-critical quenching(TIQ) at 800 ℃ for enhancing its strength–ductility balance. Both heat-treated alloy steels have the martensite–ferrite dual-phase(DP) microstructures. The volume fractions of martensite in the two treated alloy steels are nearly similar(～ 85 vol%), while the sizes of the prior austenitic grain for martensite are different. The martensite-dominated DP microstructure resulted in an obvious improvement in strength–ductility balance of the alloy steel. Compared with the DQ treatment, the multi-step TIQ treatment caused the strength–ductility balance of the alloy steel to be enhanced due to its higher total elongation. The better ductility of the TIQ-treated alloy steel can be attributed to the optimization of the microstructure. The preferred orientation of ferritic grain in the as-deposited alloy steel which was adverse to plastic deformation through dislocation slip was eliminated via the multi-step TIQ treatment. Moreover, the TIQ treatment promoted the formation of finer-grained martensite with larger areas of grain boundaries and twinning boundaries which resulted in the enhancement of the coordinated deformability of the martensite with the ferrite.     

Room temperature tensile deformation behavior of a Ni-based superalloy with high W content

K416B Ni-based superalloy with high W content has good high temperature properties and low cost, which has a great development potential. To investigate the room temperature tensile property and the deformation feature of K416B superalloy, tensile testing at room temperature was carried out, and optical microscopy (OM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to analyze the deformation and damage mechanisms. Results show that the main room temperature tensile deformation features of the K416B nickel-based superalloy are dislocations slipping in the matrix and shearing into γ′ phase. The <110> super-dislocations shearing into γ′ phase can form the anti-phase boundary two coupled (a/2)<110> partial-dislocations or decompose into the configuration of two (a/3)<112> partial dislocations plus stacking fault. In the later stage of tensile testing, the slip-lines with different orientations are activated in the grain, causing the stress concentration in the regions of block carbide or the porosity, and cracks initiate and propagate along these regions.

     

奥氏体化及回火温度对E550级低温钢组织和性能的影响

利用光学显微镜、扫描电镜、拉伸和冲击试验机等手段,研究了E550级高强度钢850~1000 ℃系列奥氏体化温度下组织演变规律和不同回火温度下的组织性能。建立了奥氏体化温度与奥氏体晶粒尺寸的数学关系模型,模型计算结果与实测值高度吻合。检测了不同奥氏体化温度试板分别在600 ℃和670 ℃回火后的组织和力学性能,结果表明:奥氏体化温度选择880~930 ℃范围得到原奥氏体晶粒均匀细小,配合670 ℃回火,得到的综合性能优良。     

热处理对铬钼钢刀具畸变的影响

对25CrMo、30CrMo和42CrMo钢刀具进行了860 ℃淬火工艺试验,且对42CrMo钢刀具进行860、850、830 ℃淬火及预热+830 ℃淬火试验,对比了刀槽的畸变量。结果表明:随着碳含量增加,低中碳铬钼钢刀槽860 ℃淬火时刀槽畸变量呈上升趋势,最大畸变量在－0.15~+0.15 mm波动。随着淬火温度的降低,42CrMo钢刀槽畸变量下降到－0.10~+0.09 mm,增加预处理对刀槽畸变量无显著影响。     

汽车用超高强度钢的合金化方式及组织控制

超高强度钢因其优异的强度及塑韧性而在汽车行业得到广泛应用。针对汽车用超高强度钢,详细介绍了其合金化方式及强化机制,并详细阐述了奥氏体相及其相变所产生的组织增塑效应,以及对组织的调控方法。     

30CrNi3MoV钢动态再结晶行为及其模型的构建

根据Gleeble-3500热模拟试验机测量30CrNi3MoV钢的真应力-真应变曲线,系统研究了应变速率为0.01、0.1 s^-1时钢材的动态再结晶行为,并构建了其动态再结晶模型。结果表明:30CrNi3MoV钢在高温小应变速率下更容易发生动态再结晶,其热变形激活能为328.2 kJ/mol;通过加工硬化率随流变应力变化曲线(θ-σ)的拐点确定临界应变,可得动态再结晶临界应变方程为ε_c=0.001 22Z^0.175;构建的动态再结晶体积分数及其平均晶粒尺寸模型能够较好地预测试验钢的动态再结晶体积分数及其晶粒尺寸;当应变速率为0.1 s^-1、变形温度为1050 ℃时,试验钢的晶粒最细小、均匀,平均晶粒尺寸约为19.9 μm。